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Preparation of biomass-derived carbon loaded with MnO as lithium-ion battery anode for improving its

《化学科学与工程前沿（英文）》 2023年 第18卷 第1期 doi: 10.1007/s11705-023-2376-y

摘要： Biomass-derived carbon materials for lithium-ion batteries emerge as one of the most promising anodes from sustainable perspective. However, improving the reversible capacity and cycling performance remains a long-standing challenge. By combining the benefits of K2CO3 activation and KMnO4 hydrothermal treatment, this work proposes a two-step activation method to load MnO2 charge transfer onto biomass-derived carbon (KAC@MnO2). Comprehensive analysis reveals that KAC@MnO2 has a micro-mesoporous coexistence structure and uniform surface distribution of MnO2, thus providing an improved electrochemical performance. Specifically, KAC@MnO2 exhibits an initial charge-discharge capacity of 847.3/1813.2 mAh·g–1 at 0.2 A·g–1, which is significantly higher than that of direct pyrolysis carbon and K2CO3 activated carbon, respectively. Furthermore, the KAC@MnO2 maintains a reversible capacity of 652.6 mAh·g–1 after 100 cycles. Even at a high current density of 1.0 A·g–1, KAC@MnO2 still exhibits excellent long-term cycling stability and maintains a stable reversible capacity of 306.7 mAh·g–1 after 500 cycles. Compared with reported biochar anode materials, the KAC@MnO2 prepared in this work shows superior reversible capacity and cycling performance. Additionally, the Li+ insertion and de-insertion mechanisms are verified by ex situ X-ray diffraction analysis during the charge-discharge process, helping us better understand the energy storage mechanism of KAC@MnO2.

关键词： biomass-derived carbon     MnO2     lithium-ion batteries     anode material     high reversible capacity    

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Algal biomass derived biochar anode for efficient extracellular electron uptake from

Yan-Shan Wang, Dao-Bo Li, Feng Zhang, Zhong-Hua Tong, Han-Qing Yu

《环境科学与工程前沿（英文）》 2018年 第12卷 第4期 doi: 10.1007/s11783-018-1072-5

摘要：

Algal biochar anode produced higher biocurrent compared with graphite plate anode.

Algal biochar exhibited stronger electrochemical response to redox mediators.

Algal biochar showed excellent adsorption to redox mediators.

关键词： Algal biochar     Anode material     Electrochemical activity     Extracellular electron transport     Waste resource utilization    

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TiO supported IrO for anode reversal tolerance in proton exchange membrane fuel cell

《能源前沿（英文）》 2022年 第16卷 第5期   页码 852-861 doi: 10.1007/s11708-021-0811-7

摘要： Fuel starvation can occur and cause damage to the cell when proton exchange membrane fuel cells operate under complex working conditions. In this case, carbon corrosion occurs. Oxygen evolution reaction (OER) catalysts can alleviate carbon corrosion by introducing water electrolysis at a lower potential at the anode in fuel shortage. The mixture of hydrogen oxidation reaction (HOR) and unsupported OER catalyst not only reduces the electrolysis efficiency, but also influences the initial performance of the fuel cell. Herein, Ti4O7 supported IrOx is synthesized by utilizing the surfactant-assistant method and serves as reversal tolerant components in the anode. When the cell reverse time is less than 100 min, the cell voltage of the MEA added with IrOx/Ti4O7 has almost no attenuation. Besides, the MEA has a longer reversal time (530 min) than IrOx (75 min), showing an excellent reversal tolerance. The results of electron microscopy spectroscopy show that IrOx particles have a good dispersity on the surface of Ti4O7 and IrOx/Ti4O7 particles are uniformly dispersed on the anode catalytic layer. After the stability test, the Ti4O7 support has little decay, demonstrating a high electrochemical stability. IrOx/Ti4O7 with a high dispersity has a great potential to the application on the reversal tolerance anode of the fuel cell.

关键词： proton exchange membrane fuel cell (PEMFC)     fuel starvation     cell reverse     reversal tolerance anode     oxygen evolution reaction    

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One-step synthesis of recoverable CuCo

Tongzhou Lu, Yongzheng Zhang, Chun Cheng, Yanbin Wang, Yongming Zhu

《化学科学与工程前沿（英文）》 2020年 第14卷 第4期   页码 595-604 doi: 10.1007/s11705-019-1818-z

摘要： A facile one-step hydrothermal method has been adopted to directly synthesize the CuCo S material on the surface of Ni foam. Due to the relatively large specific surface area and wide pore size distribution, the CuCo S material not only effectively increases the reactive area, but also accommodates more side reaction products to avoid the difficulty of mass transfer. When evaluated as anode for Li-ion batteries, the CuCo S material exhibits excellent electrochemical performance including high discharge capacity, outstanding cyclic stability and good rate performance. At the current density of 200 mA·g , the CuCo S material shows an extremely high initial discharge capacity of 2510 mAh·g , and the cycle numbers of the material even reach 83 times when the discharge capacity is reduced to 500 mAh·g . Furthermore, the discharge capacity can reach 269 mAh·g at a current of 2000 mA·g . More importantly, when the current density comes back to 200 mA·g , the discharge capacity could be recovered to 1436 mAh·g , suggesting an excellent capacity recovery characteristics.

关键词： copper cobalt sulfide     recoverability     one-step hydrothermal method     anode material     Li-ion battery    

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Three-dimensional composite Li metal anode by simple mechanical modification for high-energy batteries

《能源前沿（英文）》 2023年 第17卷 第5期   页码 569-584 doi: 10.1007/s11708-023-0875-7

摘要： Lithium (Li) metal is believed to be the “Holy Grail” among all anode materials for next-generation Li-based batteries due to its high theoretical specific capacity (3860 mAh/g) and lowest redox potential (−3.04 V). Disappointingly, uncontrolled dendrite formation and “hostless” deposition impede its further development. It is well accepted that the construction of three-dimensional (3D) composite Li metal anode could tackle the above problems to some extent by reducing local current density and maintaining electrode volume during cycling. However, most strategies to build 3D composite Li metal anode require either electrodeposition or melt-infusion process. In spite of their effectiveness, these procedures bring multiple complex processing steps, high temperature, and harsh experimental conditions which cannot meet the actual production demand in consideration of cost and safety. Under this condition, a novel method to construct 3D composite anode via simple mechanical modification has been recently proposed which does not involve harsh conditions, fussy procedures, or fancy equipment. In this mini review, a systematic and in-depth investigation of this mechanical deformation technique to build 3D composite Li metal anode is provided. First, by summarizing a number of recent studies, different mechanical modification approaches are classified clearly according to their specific procedures. Then, the effect of each individual mechanical modification approach and its working mechanisms is reviewed. Afterwards, the merits and limits of different approaches are compared. Finally, a general summary and perspective on construction strategies for next-generation 3D composite Li anode are presented.

关键词： lithium (Li)-ion battery (LIB)     Li metal battery     three-dimensional (3D) composite Li metal anode     mechanical modification     reducing local current density    

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Synthesis of Chl@Ti

Wenxin Xu, Xin Zhao, Jiali Tang, Chao Zhang, Yu Gao, Shin-ichi Sasaki, Hitoshi Tamiaki, Aijun Li, Xiao-Feng Wang

《化学科学与工程前沿（英文）》 2021年 第15卷 第3期   页码 709-716 doi: 10.1007/s11705-020-1984-z

摘要： Two-dimensional (2D) titanium carbide MXene Ti C has attracted significant research interest in energy storage applications. In this study, we prepared Chl@Ti C composites by simply mixing a chlorophyll derivative (e.g., zinc methyl 3-devinyl-3-hydroxymethyl- pyropheophorbide (Chl)) and Ti C in tetrahydrofuran, where the Chl molecules were aggregated among the multi-layered Ti C MXene or on its surface, increasing the interlayer space of Ti C . The as-prepared Chl@Ti C was employed as the anode material in the lithium-ion battery (LIB) with lithium metal as the cathode. The resulting LIB exhibited a higher reversible capacity and longer cycle performance than those of LIB based on pure Ti C , and its specific discharge capacity continuously increased along with the increasing number of cycles, which can be attributed to the gradual activation of Chl@Ti C accompanied by the electrochemical reactions. The discharge capacity of 1 wt-% Chl@Ti C was recorded to be 325 mA·h·g at the current density of 50 mA·g with a Coulombic efficiency of 56% and a reversible discharge capacity of 173 mA·h·g at the current density of 500 mA·g after 800 cycles. This work provides a novel strategy for improving the energy storage performance of 2D MXene materials by expanding the layer distance with organic dye aggregates.

关键词： zinc chlorin aggregate     Ti3C2 MXene     anode material     lithium storage    

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中国铝工业应用新型电极材料的研究与展望

邱竹贤

《中国工程科学》 2001年 第3卷 第5期   页码 50-54

摘要：

介绍了现代铝工业上新近开发研制的几种电极材料，涉及惰性阴极、惰性阳极、双极性电极等；还研制了低温电解质，使电解温度降低到800～900℃。如果惰性电极与低温电解质配合起来应用，则能够明显减少工业铝生产中的物料消耗，节省电能，增大电解槽生产能力，并改善环境状况，可望大幅度降低生产成本。

关键词： 惰性阳极     惰性阴极     SiC绝缘侧壁     低温铝电解    

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21世纪伊始铝电解工业的新进展

邱竹贤

《中国工程科学》 2003年 第5卷 第4期   页码 41-46

摘要：

21世纪伊始，法国500kA特大型预焙阳极电解槽，以及中国320 kA大型电解槽的出现，标志着铝电解工业的重要新进展。文章从理论上分析了大型电解槽的优越性，论述了减少电解槽的热损失系数，即减少按单位电量核算的热损失量，便是大型槽能够节省电能的理论基础；应用低温铝电解和惰性电极是铝电解工业今后的发展方向。

关键词： 铝电解工业     大型电解槽     低温铝电解     惰性阳极和惰性阴极    

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铝电解用Fe-Ni-Co-Al2O3金属陶瓷惰性阳极

邱竹贤,石忠宁,徐君莉

《中国工程科学》 2004年 第6卷 第8期   页码 35-39

摘要：

研制了一种新型铝电解金属陶瓷惰性阳极，阳极基体由Fe-Ni-CoAl2O3构成。在石墨坩埚中，960℃温度下，电解质中的氧化铝质量分数为6.0%，摩尔比为2.6；阳极电流密度为1.0 A/cm2，阳极尺寸大小为120 mm×80 mm×15 mm，石墨阴极尺寸大小为120 mm×40 mm×20 mm，通入的直流电为100～300 A，电解时间各为10 h；实验所得的电解铝产品纯度达到98%以上，杂质主要为Fe，Ni，Co；电解后的阳极外观尺寸无明显变化，阳极气体中氧气质量分数达到98%～99%。阳极的反电动势为2.45 V，比理论分解电压仅高出0.25 V证明该阳极为惰性阳极，在电解槽中进行的是Al2O3的分解反应。

关键词： 铝电解     惰性阳极     反电动势    

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controlled synthesis of hierarchically structured mesoporous Li4Ti5O12/C/rGO composites as high-performance anode

Cehuang FU, Shuiyun SHEN, Ruofei WU, Xiaohui YAN, Guofeng XIA, Junliang ZHANG

《能源前沿（英文）》 2022年 第16卷 第4期   页码 607-612 doi: 10.1007/s11708-021-0798-0

摘要： In this paper, a facile strategy is proposed to controllably synthesize mesoporous Li4Ti5O12/C nanocomposite embedded in graphene matrix as lithium-ion battery anode via the co-assembly of Li4Ti5O12 (LTO) precursor, GO, and phenolic resin. The obtained composites, which consists of a LTO core, a phenolic-resin-based carbon shell, and a porous frame constructed by rGO, can be denoted as LTO/C/rGO and presents a hierarchical structure. Owing to the advantages of the hierarchical structure, including a high surface area and a high electric conductivity, the mesoporous LTO/C/rGO composite exhibits a greatly improved rate capability as the anode material in contrast to the conventional LTO electrode.

关键词： Li4Ti5O12     phenolic-resin-based carbon     mesoporous composite     graphene    

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铜阳极泥预处理连续加压酸浸工艺开发研究

王吉坤,冯桂林

《中国工程科学》 2009年 第11卷 第5期   页码 18-22

摘要：

绍了新开发出来的一种具有较好工业应用前景的铜阳极泥预处理新工艺，小型及半工业试验结果表明，铜阳极泥直接加压酸浸，可以充分利用生阳极泥中水溶性铜离子的催化氧化作用，提高反应速度；在连续浸出过程中Ag，Se，Te走向与间断浸出过程差别明显，使浸出效果优于间断加压浸出预处理工艺，有利于提高有价元素的综合回收。

关键词： 铜阳极泥     综合利用     加压酸浸     连续浸出    

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Preparing graphene from anode graphite of spent lithium-ion batteries

Wenxuan Zhang, Zhanpeng Liu, Jing Xia, Feng Li, Wenzhi He, Guangming Li, Juwen Huang

《环境科学与工程前沿（英文）》 2017年 第11卷 第5期 doi: 10.1007/s11783-017-0993-8

摘要： With extensive use of lithium ion batteries (LIBs), amounts of LIBs were discarded, giving rise to growth of resources demand and environmental risk. In view of wide usage of natural graphite and the high content (12%–21%) of anode graphite in spent LIBs, recycling anode graphite from spent LIBs cannot only alleviate the shortage of natural graphite, but also promote the sustainable development of related industries. After calcined at 600°Cfor 1 h to remove organic substances, anode graphite was used to prepare graphene by oxidation-reduction method. Effect of pH and N2H4·H2O amount on reduction of graphite oxide were probed. Structure of graphite, graphite oxide and graphene were characterized by XRD, Raman and FTIR. Graphite oxide could be completely reduced to graphene at pH 11 and 0.25 mL N2H4·H2O. Due to the presence of some oxygen-containing groups and structure defects in anode graphite, concentrated H2SO4 and KMnO4 consumptions were 40% and around 28.6% less than graphene preparation from natural graphite, respectively.

关键词： Spent LIBs     Graphite     Graphite oxide     Grapheme    

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Liquid metal material genome: Initiation of a new research track towards discovery of advanced energy

Lei WANG, Jing LIU

《能源前沿（英文）》 2013年 第7卷 第3期   页码 317-332 doi: 10.1007/s11708-013-0271-9

摘要： As the basis of modern industry, the roles materials play are becoming increasingly vital in this day and age. With many superior physical properties over conventional fluids, the low melting point liquid metal material, especially room-temperature liquid metal, is recently found to be uniquely useful in a wide variety of emerging areas from energy, electronics to medical sciences. However, with the coming enormous utilization of such materials, serious issues also arise which urgently need to be addressed. A biggest concern to impede the large scale application of room-temperature liquid metal technologies is that there is currently a strong shortage of the materials and species available to meet the tough requirements such as cost, melting point, electrical and thermal conductivity, etc. Inspired by the Material Genome Initiative as issued in 2011 by the United States of America, a more specific and focused project initiative was proposed in this paper—the liquid metal material genome aimed to discover advanced new functional alloys with low melting point so as to fulfill various increasing needs. The basic schemes and road map for this new research program, which is expected to have a worldwide significance, were outlined. The theoretical strategies and experimental methods in the research and development of liquid metal material genome were introduced. Particularly, the calculation of phase diagram (CALPHAD) approach as a highly effective way for material design was discussed. Further, the first-principles (FP) calculation was suggested to combine with the statistical thermodynamics to calculate the thermodynamic functions so as to enrich the CALPHAD database of liquid metals. When the experimental data are too scarce to perform a regular treatment, the combination of FP calculation, cluster variation method (CVM) or molecular dynamics (MD), and CALPHAD, referred to as the mixed FP-CVM-CALPHAD method can be a promising way to solve the problem. Except for the theoretical strategies, several parallel processing experimental methods were also analyzed, which can help improve the efficiency of finding new liquid metal materials and reducing the cost. The liquid metal material genome proposal as initiated in this paper will accelerate the process of finding and utilization of new functional materials.

关键词： liquid metal material genome     energy material     material discovery     advanced material     room-temperature liquid alloy     thermodynamics     phase diagram    

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Role of oxygen vacancy inducer for graphene in graphene-containing anodes

《化学科学与工程前沿（英文）》 2023年 第17卷 第3期   页码 326-333 doi: 10.1007/s11705-022-2213-8

摘要： Currently, graphene is only considered as a conductive additive and expansion inhibitor in oxides/graphene composite anodes. In this study, a new graphene role (oxygen vacancy inducer) in graphene/oxides composites anodes, which are treated at high-temperature, is proposed and verified using experiments and density functional theory calculations. During high-temperature processing, graphene forms carbon vacancies due to increased thermal vibration, and the carbon vacancies capture oxygen atoms, facilitating the formation of oxygen vacancies in oxides. Moreover, the induced oxygen vacancy concentrations can be regulated by sintering temperatures, and the behavior is unaffected by oxide crystal structures (crystalline and amorphous) and morphology (size and shape). According to density functional theory calculations and electrochemical measurements, the oxygen vacancies enhance the lithium-ion storage performance. The findings can result in a better understanding of graphene’s roles in graphene/oxide composite anodes, and provide a new method for designing high-performance oxide anodes.

关键词： oxide     oxygen vacancy     graphene     anode     density functional theory calculation    

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Robust topology optimization of multi-material lattice structures under material and load uncertainties

Yu-Chin CHAN, Kohei SHINTANI, Wei CHEN

《机械工程前沿（英文）》 2019年 第14卷 第2期   页码 141-152 doi: 10.1007/s11465-019-0531-4

摘要： Enabled by advancements in multi-material additive manufacturing, lightweight lattice structures consisting of networks of periodic unit cells have gained popularity due to their extraordinary performance and wide array of functions. This work proposes a density-based robust topology optimization method for meso- or macro-scale multi-material lattice structures under any combination of material and load uncertainties. The method utilizes a new generalized material interpolation scheme for an arbitrary number of materials, and employs univariate dimension reduction and Gauss-type quadrature to quantify and propagate uncertainty. By formulating the objective function as a weighted sum of the mean and standard deviation of compliance, the tradeoff between optimality and robustness can be studied and controlled. Examples of a cantilever beam lattice structure under various material and load uncertainty cases exhibit the efficiency and flexibility of the approach. The accuracy of univariate dimension reduction is validated by comparing the results to the Monte Carlo approach.

关键词： robust topology optimization     lattice structures     multi-material     material uncertainty     load uncertainty     univariate dimension reduction    

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标题 作者 时间 类型 操作

Preparation of biomass-derived carbon loaded with MnO as lithium-ion battery anode for improving its

期刊论文

Algal biomass derived biochar anode for efficient extracellular electron uptake from

Yan-Shan Wang, Dao-Bo Li, Feng Zhang, Zhong-Hua Tong, Han-Qing Yu

期刊论文

TiO supported IrO for anode reversal tolerance in proton exchange membrane fuel cell

期刊论文

One-step synthesis of recoverable CuCo

Tongzhou Lu, Yongzheng Zhang, Chun Cheng, Yanbin Wang, Yongming Zhu

期刊论文

Three-dimensional composite Li metal anode by simple mechanical modification for high-energy batteries

期刊论文

Synthesis of Chl@Ti

Wenxin Xu, Xin Zhao, Jiali Tang, Chao Zhang, Yu Gao, Shin-ichi Sasaki, Hitoshi Tamiaki, Aijun Li, Xiao-Feng Wang

期刊论文

中国铝工业应用新型电极材料的研究与展望

邱竹贤

期刊论文

21世纪伊始铝电解工业的新进展

邱竹贤

期刊论文

铝电解用Fe-Ni-Co-Al2O3金属陶瓷惰性阳极

邱竹贤,石忠宁,徐君莉

期刊论文

controlled synthesis of hierarchically structured mesoporous Li4Ti5O12/C/rGO composites as high-performance anode

Cehuang FU, Shuiyun SHEN, Ruofei WU, Xiaohui YAN, Guofeng XIA, Junliang ZHANG

期刊论文

铜阳极泥预处理连续加压酸浸工艺开发研究

王吉坤,冯桂林

期刊论文

Preparing graphene from anode graphite of spent lithium-ion batteries

Wenxuan Zhang, Zhanpeng Liu, Jing Xia, Feng Li, Wenzhi He, Guangming Li, Juwen Huang

期刊论文

Liquid metal material genome: Initiation of a new research track towards discovery of advanced energy

Lei WANG, Jing LIU

期刊论文

Role of oxygen vacancy inducer for graphene in graphene-containing anodes

期刊论文

Robust topology optimization of multi-material lattice structures under material and load uncertainties

Yu-Chin CHAN, Kohei SHINTANI, Wei CHEN

期刊论文